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Updated: Jul 8, 2025

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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重新审视Peri-Aryloxyquinones:从一个被遗忘的光色系统到新兴应用的有希望的工具

Andrey G Lvov1,2, Lyubov S Klimenko3, Vasily N Bykov1,2

  • 1A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky, St., Irkutsk, 664033, Russia.

Chemistry (Weinheim an der Bergstrasse, Germany)
|December 12, 2023
PubMed
概括

环基 (PAQs) 是具有光诱导分子迁移的光开关. 这些化合物显示出开发新的可光控制材料和设备的希望,因为它们的固态光色.

关键词:
这是一种氨酸 (Anthraquinone).亚里洛特罗皮性 (arylotropy) 是一种类型.这是光色染色主义.照片交换换换照片交换奇诺是一种氨酸.

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In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
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Phase I biotransformation, or functionalization, is a crucial chemical process that converts drugs and other xenobiotics into more water-soluble forms, facilitating expulsion from the body. It involves oxidative, reductive, and hydrolytic reactions that add or unveil polar functional groups on lipophilic substrates. Key players in phase I reactions are the mixed-function oxidases. Situated in liver cell microsomes, these enzymes predominantly carry out drug metabolism. They require molecular...
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