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Updated: Jul 8, 2025

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
12:07

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes

Published on: April 1, 2013

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通过可见光介导的异性和区域选择性侧面功能失调,用于用酸硫处理的酸

Lorenzo Di Terlizzi1,2, Luca Nicchio1,2, Camilla Callegari1,2

  • 1Institut de Chimie des Substances Naturelles (ICSN), CNRS UPR 2301, Université Paris-Saclay, 1 avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex, France.

Organic letters
|December 12, 2023
PubMed
概括

可见光激活了非催化剂反应的亚里拉佐硫. 这项研究介绍了一种简单的方法来使烯失去功能,从而产生有价值的α-硫烯烯和1,2-氧化产品,用于异环合成.

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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