高分散的无形纳米功能化碳纳米纤维气凝用于高效吸收和固定Hg(II) 离子
Dongmin Zhao1, Zhuoyan Li1, Kaini Zhu1
1State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, People's Republic of China.
Journal of hazardous materials
|December 12, 2023
概括
新的Se/CNF气凝有效捕获有毒的 (Hg) 离子. 这些材料最大限度地增加了.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学 化学 化学
背景情况:
- 含有 (Se) 的材料在去除 (Hg (II)) 离子方面表现有前途.
- 元素Se提供了高的Se比率,但在现场暴露和利用效率方面面临挑战.
研究的目的:
- 开发Se/CNF气凝,以高效地吸收和固定Hg (II) 离子.
- 为了提高元素Se在整治中的利用效率.
主要方法:
- 合理设计Se/CNF气凝结构,分散性和大小.
- 在3D多孔纤维素纳米纤维 (CNF) 气凝中制备分散良好的无形纳米-Se.
- 评估Hg(II) 离子结合能力,容量,选择性和Se利用效率.
主要成果:
- 对于Hg,Se/CNF气凝具有强大的结合 (Kd = 3.8 × 105 mL·g-1) 和高容量 (943.4 mg·g-1) .
- 在99.5%的Se利用效率下,实现了对Hg(II) (αMHg > 100) 的卓越选择性.
- 该材料的结构有利于离子运输和操作,而稳定的HgSe则尽量减少对环境的影响.
结论:
- Se/CNF气凝为整治提供了高效和稳定的解决方案.
- 优化的材料设计最大限度地提高了Se的暴露和利用,从而获得更好的Hg (II) 吸附.
- 开发的气凝是一种有前途的吸附剂,具有最小的二次环境风险.
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