便携式X射线光器的效率,用于区分渣
Céline Tomczyk1, Nicolas Minvielle Larousse2
1Department of Art History and Archaeology, Université Paris 1 Panthéon-Sorbonne, ArScAn (Archéologies et Sciences de l'Antiquité), Nanterre, France.
Applied spectroscopy
|December 13, 2023
概括
来自Minier谷的 (Pb) 渣的分析显示,视觉上不同的黑色和灰色类型具有相似的元素组成. 这表明,尽管有巨大的差异,但这两种渣渣都来自同一个炼工艺和炉.
科学领域:
- 考古金属术是一种考古金属术.
- 材料科学 材料科学 材料科学
- 历史上的金工业
背景情况:
- 在Minier谷的挖掘中,发现了25公斤的 (Pb) 渣,视觉上可分为玻璃黑色和多孔灰色.
- 这些渣类型与在12-14世纪欧洲的Pb-银 (Ag) 金场所发现的渣类型一致,例如Mont Lozère.
- 关于产生这些废渣的特定金工艺过程的信息有限.
研究的目的:
- 为了研究来自Minier谷的Pb渣的化学成分.
- 为了确定视觉上明显的黑色和灰色废渣类型是否来自不同的金工艺.
- 评估便携式X射线光 (pXRF) 适用于分析Pb-Ag渣的适用性.
主要方法:
- 使用便携式X射线光 (pXRF) 分析218个Pb渣.
- 对元素组成的双变量和多变量统计分析.
- 扫描电子显微镜能量分散谱法 (SEM-EDS) 用于对选定样品进行比较分析.
主要成果:
- 使用pXRF进行的元素组成分析显示,黑色和灰色渣组之间没有明显的区别.
- 双变量和多变量分析都表明这两种废渣类型的来源是单一的.
- SEM-EDS证实了pXRF观察到的趋势,尽管它强调了pXRF对金属含量变化的夸大.
结论:
- 来自Minier谷的黑色和灰色渣很可能起源于同一类型的炉内单一的金工艺.
- pXRF是用于初步评估和比较Pb-Ag渣以确定工艺相似性的相关工具.
- 需要进一步的分析来确认矿石原产地,并阐明所采用的详细金技术.
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