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Updated: Jul 8, 2025

Time-resolved Photophysical Characterization of Triplet-harvesting Organic Compounds at an Oxygen-free Environment Using an iCCD Camera
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分子内三扩散促进三解离在五六合体中的三解离

Phillip M Greißel1, Dominik Thiel1, Henrik Gotfredsen2,3,4

  • 1Department of Chemistry and Pharmacy &, Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-University Erlangen-Nuremberg, Egerlandstraße 3, 91058, Erlangen, Germany.

Angewandte Chemie (International ed. in English)
|December 13, 2023
PubMed
概括

研究人员开发了一种新型的hexameric系统 (HexPnc) 以提高三倍生成效率. 这种分子设计模仿了固态扩散,与二维系统相比,自由三倍产量增加了多达14倍.

关键词:
橄乙烯 (Oligoacene) 是一种酸盐.光能转换 光能转换单点裂变 (singlet fission) 是一个单点裂变.三连体解离的解离方法超快速光谱法 超快速光谱法

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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