在大量再结晶的中揭示了室温超塑性
Wenshuai Chen1,2,3, Xiyao Li4, Shenbao Jin5
1State Key Laboratory of Advanced Materials for Smart Sensing, China GRINM Group Co., Ltd., Beijing, 100088, China.
Nature communications
|December 14, 2023
概括
纯 (Mo) 通过控制谷物边界的氧气来实现室温超可塑性. 耐火金属的这一突破增强了柔性,克服了要求苛刻的应用程序的脆碎断裂.
科学领域:
- 材料科学 材料科学 材料科学
- 金工业是金工业的一个方面.
- 机械工程 机械工程
背景情况:
- 身体中心的立方体耐火金属提供高温强度,但容易发生脆脆的颗粒间断裂.
- 再结晶可以导致在粒度边界 (GBs) 的微量元素丰富,加剧像 (Mo) 这样的材料的脆性.
研究的目的:
- 开发一种完全再结晶的纯 (Mo) 材料,表现出室温 (RT) 超可塑性.
- 通过对其颗粒边界组成和结构进行工程来减轻Mo中的脆性颗粒间断裂.
主要方法:
- 粉末金技术 粉末金技术
- Y型热和随后的回火工艺.
- 在谷物边界 (GBs) 的工程超低氧 (O) 度.
主要成果:
- 实现了完全再结晶的纯Mo材料,具有室温超可塑性.
- 通过控制GBs中的O度来降低GBs的脆性.
- 启用了有序失调网络开发和有效的失调传输在低角度GBs.
- 在RT时显著提高了可变形性,达到108.7%,抑制了脆性粒际骨折.
结论:
- 在GBs的超低O度对于消除Mo固有的脆性至关重要.
- 控制的GB化学,柔软的纹理和低角度的GBs的组合促进了Mo的超塑性.
- 这些发现对制造适用于恶劣环境的柔性耐火金属和合金具有广泛的影响.
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