人类,生物和光化学影响表面甲及其显著的十年 (2006-2017年) 减少在美国西北部的路易斯顿-克拉克斯顿山谷的表面甲
R Li1, B T Jobson2, M Wen2
1Idaho Department of Environmental Quality, Boise, ID, USA.
Chemosphere
|December 17, 2023
概括
与卫星数据相反,勒威斯顿-克拉克斯顿山谷的甲 (HCHO) 水平显著下降. 当地的造纸厂是主要的来源,除了生物和交通排放之外.
科学领域:
- 大气化学 大气化学
- 环境科学 环境科学
背景情况:
- 甲 (HCHO) 是一个重要的空气污染物和致癌物.
- 了解HCHO来源对于大气化学和公共健康至关重要.
研究的目的:
- 调查Lewiston-Clarkston (LC) 谷中的HCHO度和来源.
- 将地面测量与卫星数据趋势进行比较.
- 确定该地区HCHO水平的关键贡献者.
主要方法:
- 在2016年和2017年7月对HCHO和相关化合物的现场测量.
- 积极矩阵因子化 (PMF) 建模以识别HCHO来源.
- 当前地面测量与历史数据和卫星观测的比较.
主要成果:
- 平均HCHO度下降到2-5ppb,从2006年的10-20ppb大幅下降.
- 卫星数据显示了日益增长的趋势,突出了解决小山谷的局限性.
- PMF确定了造纸厂的排放,二次形成,生物源和交通作为主要的HCHO贡献者.
- 造纸厂的排放导致了早晨的HCHO峰值 (6-19 ppb).
- 生物的VOC受到了周围国家森林的影响.
结论:
- 地面HCHO在LC山谷下降,与卫星趋势形成鲜明对比.
- 当地工业排放 (造纸厂) 显著影响山谷的HCHO水平.
- 这些发现对于HCHO控制策略和未来大气研究至关重要.
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