从含的粘土矿物溶液中分离,使用节能膜溶剂提取
Priyesh Wagh1, Syed Z Islam1, Tej Nath Lamichhane1
1Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States.
ACS omega
|December 18, 2023
概括
这项研究引入了一种新的膜溶剂提取 (MSX) 工艺,用于从粘土矿物中有效地回收. 这种创新方法实现了高产量和纯度,这对于清洁能源应用至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 水电金术是指用水电金术进行金术.
背景情况:
- 从粘土矿物中回收 (Li) 对于清洁能源技术至关重要.
- 目前用于从 (Al) 中分离的现有方法可能是低效的.
- 需要开发先进的提取技术,以获得高纯度的.
研究的目的:
- 研究一种用于回收的新型膜溶剂提取 (MSX) 工艺.
- 选择性地将Li从Al中分离使用二-2-乙基) 酸 (DEHPA).
- 评估通过MSX工艺获得的的效率和纯度.
主要方法:
- 使用氧化吸附剂从粘土矿物溶液中选择性提取.
- 在稀释的H2SO4.4中溶解二氧化硫酸盐 (LDH硫酸盐) 的二氧化硫酸盐.
- 膜溶剂提取 (MSX) 在微孔膜中固定DEHPA,以持续去除Al.
主要成果:
- 优化MSX工艺条件:pH值为3,2mol/L H2SO4条形溶液,30%v/v的DEHPA在Isopar-L.中.
- 实现了大约92%的Li收益率.
- 获得的纯度为94%.
结论:
- MSX工艺是一种高效和选择性的回收和从粘土矿物中分离的方法.
- 这种创新技术为生产高纯度提供了一种节省时间和能源的方法.
- 开发的MSX工艺具有在离子电池和其他清洁能源技术中应用的巨大潜力.
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