在基核燃料中测定的衰变相关光
1Radioanalytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India.
ACS omega
|December 18, 2023
概括
一种新的时间分辨率光谱法准确地确定燃料中的. 这种简单,具有成本效益的技术提高了灵敏度,减少了样本大小,并最大限度地减少了浪费.
科学领域:
- 分析化学 分析化学
- 核化学 核化学 核化学
- 频谱学是一种光谱学.
背景情况:
- 精确的测定对于基核燃料至关重要.
- 传统方法面临的挑战是重叠的光谱和高背景光.
- 核燃料分析需要敏感和选择性的分析技术.
研究的目的:
- 开发一种新的,简单的,灵敏的,具有成本效益的测定方法.
- 使用时间分辨率光谱法来克服光谱干扰.
- 提供一种适用于基核燃料的方法,包括缩样本.
主要方法:
- 与染色酸的复合,一种光联结体.
- 时间分辨率光谱的应用,以区分连接体和复杂的衰变时间.
- 使用衰变相关光谱 (DAS) 来消除连接体光背景.
- 使用基于U3O8的ILCE标准进行验证,并对缩燃料样本进行分析.
主要成果:
- 实现了广泛的线性动态范围 (5-100 ppb),具有出色的线性 (r2 > 0.998).
- 证明了高精度 (10ppb时<5%,50ppb时<4%) 和低检测极限 (1.5ppb).
- 在样本中报告了高回收率 (>94%) 的酸.
结论:
- 开发的时间分辨率光方法为燃料中的确定提供了更高的灵敏度和选择性.
- 减少样本大小要求,导致从分析废物中减少回收.
- 消除了对有机溶剂的需求,使该方法更加环保和成本效益.
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