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Updated: Jul 8, 2025

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多电子旋转集群启用了使用硫化BDPA的动态核极化

Celeste Tobar1, Kaitlin Albanese2, Raj Chaklashiya2

  • 1Department of Chemistry and Biochemistry, University of California, Santa Barbara 93106, California, United States.

The journal of physical chemistry letters
|December 18, 2023
PubMed
概括

在α,γ-bisdiphenylene-β-phenylallyl (BDPA) 变体中的电子自旋聚类解释了它们高效的动态核极化 (DNP) 性能. 这种机制涉及合旋转和电子-电子交叉声,增强了低微波功率的固态核磁共振 (NMR) 信号.

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