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An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
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应变驱动的眼镜中的Kovacs类记忆效应.

Yu Tong1, Lijian Song2,3, Yurong Gao1

  • 1CAS Key Laboratory of Magnetic Materials and Devices, and Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, China.

Nature communications
|December 18, 2023
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概括

研究人员在眼镜中发现了类似科瓦克斯的记忆效应,在这种情况下,压力最初会增加,然后在减压后降低. 玻璃材料中的这种记忆效应与集体原子运动有关,可能是普遍的.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 凝聚物质物理学 凝聚物质物理学
  • 类风病学 类风病学 类风病学

背景情况:

  • 了解复杂的放松行为对于描述眼镜的性质至关重要.
  • 由于其无序的原子结构,玻璃具有独特的机械性能.

研究的目的:

  • 为了调查和报告眼镜中的Kovacs-like记忆效应.
  • 探索影响这种记忆效应的因素及其潜在的物理起源.

主要方法:

  • 对玻璃材料进行了两步高低应变刺激.
  • 监测压力放松过程.
  • 在现场进行了同步龙X射线实验.
  • 分析了放松动力学.

主要成果:

  • 在压力从更高状态跳到更低状态后,观察到一种非单调的压力放松,其特点是最初增加,然后减少.
  • 观察到的记忆效应在第一阶段增加的应变,更高的温度和更长的刺激持续时间加剧,与高度集体的原子运动和更大的激活能量相关联.
  • 同步射线X射线数据提供了对驱动压力记忆效应的物理机制的见解.

结论:

  • 这项研究证明了眼镜中的Kovacs-like记忆效应,突出了复杂的放松动态.
  • 研究结果表明,这种压力记忆效应可能是各种类型眼镜的普遍现象.
  • 这项研究加深了对玻璃行为和放松动态的理解.