对具有不同激活器模量的地聚合物宏观机械性质和微观结构之间的关系进行研究
Yiren Wang1,2, Jihui Zhao3, Dapeng Zheng4
1School of Environment and Civil Engineering, Dongguan University of Technology & Guangdong Provincial Key Laboratory of Intelligent Disaster Prevention and Emergency Technologies for Urban Lifeline Engineering, Dongguan, 523808, China.
激活器模块显著影响飞灰基地质聚合物 (FABG) 的特性. 优化这种模量可以提高FABG材料的凝形成,微观结构和机械强度.
科学领域:
- 材料科学 材料科学 材料科学
- 地质聚合物化学 地质聚合物化学
背景情况:
- 含有废渣的飞灰基地质聚合物 (FABG) 提供了现场应用的优势.
- 激活器模量是影响FABG属性的关键参数.
研究的目的:
- 研究激活器模量 (SiO2 / Na2O比率从1.1到1.5) 对FABG特性的影响.
- 探索将激活器模块与宏观机械性质和微观结构联系在一起的机制.
主要方法:
- 用不同的激活器模量对FABG特性进行实验分析.
- 使用29Si NMR进行微结构和反应产品的表征.
主要成果:
- 早期产品是C-A-S-H凝;后期形成具有更高交叉连接的N-(C) -A-S-H凝.
- 凝中的Si/Al比率随着模量增加而下降,C-A-S-H中的MCL增加.
- 最佳的模量可以提高凝产量,微观结构密度,并减少多孔性,增加强度.
结论:
- 激活器模块批判性地控制了FABG中的凝形成和微观结构.
- 凝量与FABG强度发展有积极的相关性.
- 优化的激活器模块是高性能FABG材料的关键.
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