相关实验视频
Updated: Jul 8, 2025

08:01
The Diffusion of Passive Tracers in Laminar Shear Flow
Published on: May 1, 2018
8.6K
在蒸发的液滴中溶解原子的扩散
Fuqian Yang1, Yong Li2, Kai Zhang3
1Materials Program, Department of Chemical and Materials Engineering, University of Kentucky, Lexington, Kentucky 40506, United States.
Langmuir : the ACS journal of surfaces and colloids
|December 19, 2023
概括
控制溶剂蒸发可以使晶体和纳米粒子生长. 低溶剂损失率对于在蒸发过程中液滴中溶解物均分布至关重要.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 流体动力学 流体动力学
背景情况:
- 从液滴中控制溶剂蒸发是合成晶体,纳米粒子和微粒子的关键.
- 蒸发驱动溶解物扩散,导致超和粒子形成.
- 了解蒸发滴中的质量传输对于控制粒子特征至关重要.
研究的目的:
- 在溶剂蒸发过程中分析质量传输和溶液分布在球形液滴中.
- 为滴水蒸发的移动边界问题开发和验证近似分析解决方案.
- 确定最佳的溶剂蒸发率,以实现均的溶液分布.
主要方法:
- 利用伪稳定状态方法在蒸发的滴滴中建模质量运输.
- 为溶解物度概况推导出两个近似的分析解:一个线性函数和一个指数函数.
- 通过将它们与使用有限元法获得的数值结果进行比较,验证了近似解决方案.
主要成果:
- 导出了两个近似解决方案,并与有限元方法模拟进行了验证.
- 所得到的溶液准确地描述了溶剂蒸发过程中溶液的分布.
- 发现低溶剂蒸发率是保持均的溶液分布所必需的.
结论:
- 开发的近似解决方案提供了准确的预测,以蒸发滴滴的质量运输.
- 控制溶剂损失率对于实现均的溶液分布至关重要,这对于受控颗粒合成至关重要.
- 这项研究提供了对优化材料合成液滴蒸发过程的见解.
相关概念视频
Solution Formation
31.6K
There is no one solvent that can dissolve every type of solute. Some substances that readily dissolve in a certain solvent might be insoluble in a different solvent. A simple way to predict which substances dissolve in which solvent is the phrase "like dissolves like". This means that polar substances, such as salt and sugar, dissolve in a polar substance like water. In contrast, non-polar substances are more soluble in non-polar solvents such as carbon tetrachloride.
This selective...
This selective...
31.6K
Diffusion
192.6K
Diffusion is the passive movement of substances down their concentration gradients—requiring no expenditure of cellular energy. Substances, such as molecules or ions, diffuse from an area of high concentration to an area of low concentration in the cytosol or across membranes. Eventually, the concentration will even out, with the substance moving randomly but causing no net change in concentration. Such a state is called dynamic equilibrium, which is essential for maintaining overall...
192.6K
Theories of Dissolution: Diffusion Layer Model
773
Dissolution, the process by which drug particles dissolve in a solvent, is explained by the diffusion layer model, a theoretical framework that simulates the absorption of oral drugs and allows us to analyze experimental data.
This process starts with a thin layer, saturated with the drug, forming at the interface between the solid and liquid. The solute then diffuses from this layer into the main solution. The Noyes-Whitney equation suggests that the rate of dissolution relies on the diffusion...
This process starts with a thin layer, saturated with the drug, forming at the interface between the solid and liquid. The solute then diffuses from this layer into the main solution. The Noyes-Whitney equation suggests that the rate of dissolution relies on the diffusion...
773
Behavior of Gas Molecules: Molecular Diffusion, Mean Free Path, and Effusion
29.0K
Although gaseous molecules travel at tremendous speeds (hundreds of meters per second), they collide with other gaseous molecules and travel in many different directions before reaching the desired target. At room temperature, a gaseous molecule will experience billions of collisions per second. The mean free path is the average distance a molecule travels between collisions. The mean free path increases with decreasing pressure; in general, the mean free path for a gaseous molecule will be...
29.0K
Vapor Pressure Lowering
26.7K
The equilibrium vapor pressure of a liquid is the pressure exerted by its gaseous phase when vaporization and condensation are occurring at equal rates:
Dissolving a nonvolatile substance in volatile liquid results in a lowering of the liquid’s vapor pressure. This phenomenon can be explained by considering the effect of added solute molecules on the liquid's vaporization and condensation processes. To vaporize, solvent molecules must be present at the surface of the solution....
Dissolving a nonvolatile substance in volatile liquid results in a lowering of the liquid’s vapor pressure. This phenomenon can be explained by considering the effect of added solute molecules on the liquid's vaporization and condensation processes. To vaporize, solvent molecules must be present at the surface of the solution....
26.7K
Vaporization
34.7K
The physical form of a substance changes by changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. For vaporization to occur, kinetic energy must be greater than the intermolecular forces that keep molecules bonded. The amount of energy needed to vaporize a quantity of liquid at a given pressure and a constant temperature is called the heat of vaporization. When...
34.7K

