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Updated: Jul 8, 2025

Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds
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在 silico 策略设计一个高效的有机光开关,基于激发状态阴离子转移

Laure de Thieulloy1, Cédric Mongin2, Isabelle Leray2

  • 1Chimie ParisTech, CNRS, Institute of Chemistry for Life and Health Sciences (i-CLeHS), PSL Research University, F-75005 Paris, France.

Physical chemistry chemical physics : PCCP
|December 20, 2023
PubMed
概括

研究人员使用计算方法优化了光开关,以改善阴子转移,但同时增强所有属性仍然是一个挑战.

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Photochemical Electrocyclic Reactions: Stereochemistry

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Selection Rules: Photochemical Activation
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The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
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