在亚马逊上空的热带自由热带层中氧化有机分子
Qiaozhi Zha1,2, Diego Aliaga1, Radovan Krejci3
1Institute for Atmospheric and Earth System Research / Physics, University of Helsinki, Helsinki00014, Finland.
National science review
|December 20, 2023
概括
研究人员发现,来自亚马逊雨林的氧化有机分子 (OOM) 有助于热带自由热带层的新粒子形成,影响气候.
科学领域:
- 大气化学 大气化学
- 气溶科学 气溶科学
背景情况:
- 热带自由热带层 (FT) 中的新粒子形成 (NPF) 对云凝聚核 (CCN) 生产至关重要.
- 有氧化有机分子 (OOMs) 被假设在热带FT中驱动气溶形成,但缺乏直接证据.
研究的目的:
- 在热带FT中进行OOMs的第一个现场分子水平测量.
- 研究OOMs在气溶形成和纳米粒子增长中的作用.
主要方法:
- 在Chacaltaya站 (海拔5240米) 在现场进行分子水平的OOM测量. 在玻利维亚. 在玻利维亚. 在玻利维亚.
- 分析了空气质量历史,以追踪OOM的起源.
- 在气体和粒子阶段量化OOMs.
主要成果:
- 在亚马逊地区的热带FT空气中检测到OOM,主要是4-5个碳原子.
- 建立了观察到的OOM和雨林中的异二烯排放之间的联系.
- 证明了OOMs对新形成的纳米粒子生长的贡献.
结论:
- 提供了热带FT中OOMs的第一个直接化学证据.
- 强调生物源排放在大陆范围的气溶形成中的重要作用.
- 进步了解热带地区的气溶气候相互作用.
相关概念视频
Radical Autoxidation
2.1K
The oxidation of an organic compound in the presence of air or oxygen is called autoxidation. For example, cumene reacts with oxygen to form hydroperoxide. Autoxidation involves initiation, propagation, and termination steps. Many organic compounds are susceptible to autoxidation—especially ethers in the presence of oxygen, which form hydroperoxides. Even though this reaction is slow, old ether bottles contain small amounts of peroxide, which leads to laboratory explosions during ether...
2.1K
Oxidation and Reduction of Organic Molecules
6.6K
Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
The removal of an electron from a molecule, results in a...
6.6K
Oxidation of Phenols to Quinones
3.1K
In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox...
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox...
3.1K
Autoxidation of Ethers to Peroxides and Hydroperoxides
7.6K
Ethers represent a class of chemical compounds that become more dangerous with prolonged storage because they tend to form explosive peroxides when standing in the air. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly oxidize to form hydroperoxides and dialkyl peroxides.
7.6K
Oxidative Cleavage of Alkenes: Ozonolysis
10.4K
In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
10.4K
Oxidation of Alcohols
13.1K
In this lesson, the oxidation of alcohols is discussed in depth. The various reagents used for oxidation of primary and secondary alcohols are detailed, and their mechanism of action is provided.
The process of oxidation in a chemical reaction is observed in any of the three forms:
The process of oxidation in a chemical reaction is observed in any of the three forms:
13.1K


