单粒子感应合等离子体质谱及其用于分析纳米粒子的变化
Zichao Zhou1, Diane Beauchemin1
1Queen's University, Department of Chemistry, 90 Bader Lane, Kingston, ON K7L 3N6, Canada. diane.beauchemin@queensu.ca.
概括
单颗粒感应合等离子体质谱法 (spICPMS) 准确测量纳米粒子质量和度. 流量注入和信号集成方法消除了对运输效率校准的需求,简化了纳米粒子分析.
科学领域:
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 单颗粒感应合等离子体质谱法 (spICPMS) 是用于纳米粒子表征的强大技术.
- 精确量化纳米粒子质量和度需要精确的校准,通常涉及样品吸收率和运输效率的确定.
研究的目的:
- 通过使用spICPMS来准确测量纳米粒子质量的方法,而不确定运输效率.
- 探索替代样本引入和校准策略,以改善spICPMS分析.
主要方法:
- 使用流量注入 (FI) 和单段流量分析 (MSFA) 结合spICPMS.
- 通过信号集成而不是信号平均化进行校准.
- 讨论了纠正仪器结算时间的策略.
- 探索了在等离子体和红外加热中用于样本引入的使用.
主要成果:
- 与spICPMS相结合的FI和MSFA可实现精确的纳米粒子质量测量,无需确定运输效率或样品吸收率.
- 通过信号集成进行校准,消除了对运输效率测量的要求.
- 采样引入系统的红外加热实现了100%的运输效率,简化了质量和度的确定.
结论:
- 替代样品引入和校准方法显著提高了spICPMS的纳米粒子量化准确性和容易性.
- 提出的技术减少了spICPMS分析的复杂性,使纳米粒子表征更容易获得.
更多相关视频
相关概念视频
Inductively Coupled Plasma–Mass Spectrometry (ICP–MS): Overview
747
In inductively coupled plasma–mass spectrometry (ICP–MS), an inductively coupled plasma (ICP) torch is used as an atomizer and ionizer. Solid samples are dissolved and volatilized before being introduced into the high-temperature argon plasma, while solution samples are nebulized and passed through the high-temperature argon plasma. Plasma dissociates the analytes and ionizes their component atoms to form a mixture of positive ions and molecular species. The positive ions are then...
747
Inductively Coupled Plasma Atomic Emission Spectroscopy: Principle
626
Inductively coupled plasma (ICP) is the most widely used plasma source in atomic emission spectroscopy (AES), also known as Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES). The ICP source, or torch, consists of three concentric quartz tubes with argon gas flowing through them. A spark from a Tesla coil initiates the ionization of argon, generating a high-temperature plasma.
The ions and electrons produced interact with the fluctuating magnetic field created by a water-cooled...
The ions and electrons produced interact with the fluctuating magnetic field created by a water-cooled...
626
Inductively Coupled Plasma-Mass Spectrometry (ICP-MS): Interferences
478
Inductively coupled plasma–mass spectrometry (ICP–MS) is a highly selective and sensitive technique for accurate elemental analysis. Though the analysis of ICP–MS mass spectra is comparatively straightforward, it is affected by spectroscopic and non-spectroscopic interferences. Spectroscopic interferences arise when the plasma contains ionic species with an m/z value the same as the analyte ion. Spectroscopic interference can be categorized as isobaric, polyatomic ions, and...
478
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation
230
Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
There are three main types of inductively coupled plasma atomic emission spectroscopy (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
230
Tandem Mass Spectrometry
1.0K
Tandem mass spectrometry is a technique that uses multiple mass analyzers in series to obtain a higher selectivity and signal-to-noise ratio for the analyte. Instruments with multiple analyzers separated by an interaction cell enable secondary fragmentation and selected study of the fragment ions.
Secondary fragmentations occur in the interaction cell and can be induced by various factors. Fragmentation induced by collision with inert gases, such as N2, Ar, He, etc., is called collision-induced...
Secondary fragmentations occur in the interaction cell and can be induced by various factors. Fragmentation induced by collision with inert gases, such as N2, Ar, He, etc., is called collision-induced...
1.0K
Atomic Emission Spectroscopy: Lab
167
AES is a powerful analytical technique, especially effective when used with plasma sources, producing abundant spectra in characteristic emission lines. The Inductively Coupled Plasma (ICP), in particular, yields superior quantitative analytical data due to its high stability, low noise, low background, and minimal interferences under optimal experimental conditions. However, newer air-operated microwave sources are emerging as promising alternatives that could be more cost-effective than...
167


