溶剂调节的特定离子效应:聚-异烯胺) 在非水性电解质中的刷子
Hayden Robertson1, Isaac J Gresham2, Andrew R J Nelson3
1College of Science, Engineering and Environment, University of Newcastle, Callaghan, New South Wales 2308, Australia.
Langmuir : the ACS journal of surfaces and colloids
|December 20, 2023
概括
非水性电解质中的特定离子在DMSO-水混合物中显著改变了聚合物的行为. 离子类型和度决定了聚合物膨胀和崩,这对于电池和冷保存等应用至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 聚合物科学 聚合物科学
背景情况:
- 了解非水性电解质及其与聚合物的相互作用对于储能和冷保存至关重要.
- 聚N-异烯胺 (PNIPAM) 刷子表现出温度依赖的胀/崩过渡,对它们的环境敏感.
研究的目的:
- 为了研究在二甲基硫氧化物 (DMSO) -水混合物中对聚乙烯-异烯胺 (PNIPAM) 刷毛行为的特定离子效应.
- 探索DMSO度和电解质组成的变化如何影响PNIPAM的热转换和溶解.
主要方法:
- 用光谱圆测量来测量PNIPAM刷子胀的变化.
- 用中子反射计来确定PNIPAM刷中的结构变化.
- 在一系列的DMSO-水混合物和电解质度中进行了实验.
主要成果:
- 在富含水的溶剂中,PNIPAM在温度上升时显示出膨胀到崩的过渡,阴离子决定稳定 (入) 或不稳定 (出).
- 在70%mol%的DMSO中,观察到崩到胀的过渡,离子效应在增加电解质度时逆转.
- 在纯的DMSO中,特定的离子作用导致了序列的逆转,酸 (SCN-) 破坏稳定,化物 (Cl-) 稳定了刷子.
结论:
- 特定的离子效应,特别是离子,在调节DMSO-水混合物中的PNIPAM刷行为方面发挥着关键作用.
- 离子效应的系列逆转归因于溶剂,离子和聚合物基质之间的复杂相互作用.
- 溶剂集群的稳定性被假设为聚合物溶解和刷响应背后的驱动力.
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