为了刺激石榴电解质基化Li-S电池的化学过程:在高负载的阴极中调制最终产品
Bin Sun1, KangKang Bao1, Panpan Wang1
1Research Center of Grid Energy Storage and Battery Application, School of Electrical and Information Engineering, Zhengzhou University, Zhengzhou 450001, P.R. China.
ACS nano
|December 20, 2023
概括
固体电解质硫电池提供电网规模的能源存储. 化物调制提高了硫阴极性能,实现了先进电池的高容量和稳定性.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 固体电解质化硫电池由于自放电和材料回收能力较低,因此对电网存储充满希望.
- 在实现高能量密度和可逆性方面仍然存在挑战,特别是在活性材料负载低和硫导电性差的情况下.
研究的目的:
- 为了提高化硫电池的能量密度和可逆性.
- 为了研究化物调制对硫阴极性能的影响.
主要方法:
- 在一个均的化复合材料阴极中利用化物调制效应.
- 使用理论计算来理解化离子相互作用.
- 测试高硫载荷电池的容量,能量密度和循环稳定性.
主要成果:
- 在硫阴极中形成小尺寸 (∼5 nm) 和低晶度放电产品.
- 每个Li-S电池的特定容量达到1.39Ah,硫含量高 (>80 mg cm−2).
- 显示了528.5Wh L-1的体积能量密度和300个周期的稳定循环,具有出色的可逆性.
结论:
- 化物调制显著提高了化硫电池的电化学性能.
- 开发的阴极材料使得高硫利用,容量和长期循环稳定性成为可能.
- 这一进步将硫电池定位为电网规模储能的可行技术.
更多相关视频
相关概念视频
Voltaic/Galvanic Cells
57.3K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
57.3K
Electrolysis
26.4K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.4K
Electrogravimetric Analysis: Overview
235
Electrogravimetric analysis measures the weight of an analyte deposited electrolytically onto a suitable working electrode. This method involves applying a potential to a pre-weighed electrode submerged in a solution, which results in the desired substance being deposited through reduction at the cathode or oxidation at the anode. The electrode's weight is recorded after deposition, and the difference in weight gives the analyte's weight in the solution.
To test the completeness of the...
To test the completeness of the...
235
Electrodeposition
638
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
638
Batteries and Fuel Cells
27.4K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.4K


