(VI) 复合物的吸附与基于聚合物的球形活性炭
Youssef-Amine Boussouga1, James Joseph1, Hryhoriy Stryhanyuk2
1Institute for Advanced Membrane Technology (IAMT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen 76344, Germany.
Water research
|December 20, 2023
概括
以聚合物为基础的球形活性炭有效地从饮用水中去除. 这种材料实现了低平衡时间,并且符合全球饮用水标准,即使来自受污染的自然来源.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 水处理 处理水的方法
背景情况:
- 饮用水中的污染对健康构成重大风险.
- 碳基吸附剂对的去除有希望.
- 聚合物基球形活性炭 (PBSAC) 提供了独特的吸附结构性质.
研究的目的:
- 研究PBSAC在水溶液中吸附的疗效.
- 在不同的条件下描述PBSAC的吸附行为.
- 为了阐明吸附剂内的物种分布.
主要方法:
- 静态吸附实验与不同的PBSAC属性和溶液化学.
- 同热和热力学计算.
- 空间飞行时间二次离子质谱 (ToF-SIMS) 用于分布分析.
主要成果:
- 单层吸附能力在28-667 mg/g之间,物理吸附能量为13-21 kJ/mol.
- 增加表面氧含量 (10%) 增强吸附,并将平衡时间缩短到2小时.
- 证明了有效地从自然水中去除,以满足德国和世卫组织的指导方针.
结论:
- PBSAC是一种高效的吸附剂,用于从饮用水中去除.
- 吸附在pH 6-8处是有利的,乌兰碳酸盐复合物在整个PBSAC结构中吸附.
- PBSAC显示出在放射性废物管理的混合处理技术中使用的潜力.
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