通过电还原和电化学沉同时去除酸和正酸盐
Chang Lu1, Yunxuan Chen1, Chendong Shuang1
1State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China.
Water research
|December 20, 2023
概括
这项研究提出了一种新的电化学工艺,用于同时从废水中去除酸盐和正酸盐. 结合电还原和酸沉方法在单室和双室电池中实现了高的去除效率.
科学领域:
- 环境科学与工程环境科学与工程
- 电化学 电化学 电化学
- 水处理技术水处理技术
背景情况:
- 酸 (NO3-N) 和正酸 (PO4-P) 是主要的水污染物,需要有效的去除.
- 电化学方法为从废水中同时清除污染物提供了一个有希望的途径.
- 现有的方法可能会面临NO3-N和PO4-P联合去除的效率和选择性方面的挑战.
研究的目的:
- 开发和评估一种联合电化学工艺,同时去除NO3-N和PO4-P.
- 调查单 (SCC) 和双 (DCC) 电池中这种集成系统的性能和潜在机制.
- 了解操作参数和污染物之间的相互作用对清除效率的影响.
主要方法:
- 同时去除NO3-N和PO4-P使用电还原和电化学诱导酸沉的组合.
- 在单细胞 (SCC) 和双细胞 (DCC) 中进行实验设置,以比较性能.
- 分析去除效率,阴极面积加载率,以及初始污染物度和Ca2+的影响.
主要成果:
- 实现了高清除效率:NO-N的60-90%和PO-P的80-98%在3小时内.
- 双室细胞 (DCC) 由于pH值和Ca2+度更高,PO4-P去除速度更快.
- 酸盐的减少对的去除产生了积极的影响;然而,Ca和P抑制了SCC中的酸盐的减少,特别是在较低的Ca/P比率下.
结论:
- 拟议的电化学过程有效地同时从废水中去除NO3-N和PO4-P.
- DCC配置和优化条件 (高初始Ca/P,高NO3-N) 减轻了P对NO3-N减少的抑制作用.
- 这项技术为先进的废水处理提供了可行的解决方案,解决了营养污染的挑战.
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