NaH2PO4与有机物产生协同作用,以稳定皮制厂污泥中的
Ruijie Ge1, Tao E1, Ying Cheng1
1Liaoning Key Laboratory for Chemical Clean Production, Liaoning Key Laboratory for Surface Functionalization of Titanium Dioxide Powder, Institute of Ocean Research, Institute Environmental Research, College of Chemistry and Material Engineering, Bohai University, Jinzhou, 121013, Liaoning, China.
Journal of environmental management
|December 21, 2023
概括
酸 (MSP) 和有机物质 (OM) 有效地稳定了皮厂污泥中的. 这项研究揭示了MSP和OM如何相互作用以减少和固定有毒,提供了一种新的治疗方法.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
背景情况:
- 皮革工厂污泥由于污染,造成环境风险.
- 重金属稳定对于处理含的工业废物至关重要.
研究的目的:
- 通过使用酸 (MSP) 和有机物质 (OM) 来研究厂污泥中的稳定性.
- 阐明MSP和OM相互作用以固定的机制.
主要方法:
- 用MSP和有机物质稳定的实验分析.
- 研究蒙莫里隆石 (MMT) 在稳定中的作用.
- 密度函数理论 (DFT) 计算以建模相互作用.
主要成果:
- 添加MMT和MSP显著增加可降解和可氧化的百分比.
- MSP与金属氧化物形成Cr-O键,促进内部球体的复合.
- MSP吸附到OM上,增强OM的Cr6吸附能力,并促进其降解为Cr3 .
- 酸盐离子与Cr (III) 反应,形成不溶性CrPO4沉物,减少自由的Cr (III).
结论:
- 一个涉及酸盐,OM和的三元系统被DFT计算证实.
- 负的结合能量表明被酸盐和OM共同稳定.
- 在MSP和OM的联合使用中,提供了一个有前途的策略,用于在皮厂污泥中稳定.
相关概念视频
Extraction: Advanced Methods
448
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
448
Gravimetry: Inorganic And Organic Precipitating Agents
1.3K
In gravimetry, the precipitant is chosen carefully to obtain a pure solid that can be easily filtered. Common inorganic precipitants can be used to determine several cations and anions. In some cases, the formation of the same precipitate can be used to determine the cation and the anion. For example, the reaction of barium and chromate ions to give barium chromate is used to determine both barium and chromate. However, precipitates such as hydroxides, oxalates, and metal ammonium phosphates...
1.3K
Sample Preparation for Analysis: Advanced Techniques
359
Accurate analysis of complex samples often requires advanced preparation techniques to achieve reliable and reproducible results. Samples containing inorganic or organic materials can be challenging to dissolve or decompose effectively. Standard sample preparation methods include acid digestion, fusion, dry ashing, and wet digestion.
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
359
Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride
1.8K
Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation...
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation...
1.8K
Bioremediation
18.5K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
18.5K
Factors Affecting Solubility
33.5K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
33.5K


