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在阳离子缺乏的哈夫尼亚纳米管中发光
Artem O Shilov1, Robert V Kamalov1, Maxim S Karabanalov1
1NANOTECH Centre, Ural Federal University, 19 Mira St., 620002 Yekaterinburg, Russia.
Nanomaterials (Basel, Switzerland)
|December 22, 2023
概括
氧化物 (HfO2) 纳米管由于阴离子空隙,显示出独特的光学和发光特性. 这些发现可以优化发光材料用于先进的纳米电子设备.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 固态物理 固态物理
背景情况:
- 氧化 (HfO2) 和其他高k介电材料是光电子和纳米电子的关键宽材料.
- 这些材料表现出理想的性能,如耐降解,辐射稳定性,高表面积和活跃的电子孔中心.
研究的目的:
- 研究无氧化非固态HfO2纳米管的结构,光学和发光特性.
- 在HfO2纳米管中表征阴极发光和光发光,这些纳米管具有离子子网缺陷.
主要方法:
- 化以创建HfO2纳米管.
- 在700°C时火,以达到单晶晶体结构.
- 使用光学光谱学进行带隙测量.
- 在10K和300K时进行阴极发光和光发光研究.
- 在毫秒范围内分析光发光的动力学.
主要成果:
- 确定带隙:5.65 ± 0.05 eV (无形) 和5.51 ± 0.05 eV (单临床) 的HfO2纳米管.
- 观察到一个广泛的内在发射频段,峰值为2.32.4 eV.
- 在O3f和O4f位置确定了与氧气空缺 (V0,V-,V2-) 相关的多个光学活跃的捕获和排放中心.
结论:
- 在HfO2纳米管中的阴离子空隙显著影响它们的发光特性.
- 已识别的与空缺相关的中心提供了调整发光度的见解.
- 这些发现支持优化基于哈夫尼亚的纳米管状和纳米孔状材料用于发光应用.
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