碳涂层诱导的弹性约束通过相位过渡提高离子电池的性能
Xinran Luo1, Dan Zhou1, Tianli Wu1
1Henan Key Laboratory of Photovoltaic Materials, Henan University, Kaifeng 475004, China.
ACS applied materials & interfaces
|December 22, 2023
概括
用碳涂层的化 (Sn4P3@C) 有效地解决了离子电池 (PIB) 的体积扩张问题. 这种新的阳极材料显示出用于下一代能源存储的高容量和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (PIB) 由于资源丰富和适合的电压,对大规模储能充满希望.
- 在离子插入过程中,阳极材料的显著体积膨胀阻碍了 PIB 的发展.
研究的目的:
- 为PIBs设计一种新的阳极材料,以减轻体积扩张的挑战.
- 为了提高电化学性能和基于锡的阳极的循环稳定性.
主要方法:
- 在现场采用碳涂层化 (Sn4P3@C) 作为PIB阳极材料.
- 研究碳涂层在适应应变压和防止相变中的作用.
- 电化学测试以评估容量,循环性和放电平原.
主要成果:
- Sn4P3@C通过坚固的碳状屏障有效地适应体积膨胀.
- 碳涂层在化过程中防止不良的α-Sn到β-Sn相位过渡.
- 电极表现出高可逆容量 (187 mAh g-1 超过 1500 个周期在 1 A g-1 时),良好的循环性和低放电平原.
- 由于α-Sn.的存在,观察到增强的K+扩散动态.
结论:
- Sn4P3@C是PIBs的高性能阳极材料,克服了关键的限制.
- 该研究提供了关于Sn4P3中K+的化学动力学的见解,并为基阳极开发提供了新的策略.
相关概念视频
Alkali Metals
19.3K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
19.3K
Ionic Strength: Effects on Chemical Equilibria
1.5K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
In this solution, the primary...
1.5K
Ionic Bonds
118.5K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.5K
Ionic Bonding and Electron Transfer
41.6K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.6K
Action Potential: Phases of Stimulation
5.8K
The action potential is a complex electrical event that occurs in excitable cells, such as neurons and muscle cells. It consists of several distinct phases, each with specific characteristics.
Resting Phase:
In this phase, the cell's membrane is at its resting potential, typically around -70 millivolts (mV) for neurons. Inside the cell, there is a higher concentration of potassium ions (K+) and a lower concentration of sodium ions (Na+). Voltage-gated sodium channels are closed, and...
Resting Phase:
In this phase, the cell's membrane is at its resting potential, typically around -70 millivolts (mV) for neurons. Inside the cell, there is a higher concentration of potassium ions (K+) and a lower concentration of sodium ions (Na+). Voltage-gated sodium channels are closed, and...
5.8K
MOS Capacitor
789
A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
789


