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相关概念视频

Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

14.7K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.7K
Colloidal precipitates01:09

Colloidal precipitates

585
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
585
Intermolecular Forces in Solutions02:28

Intermolecular Forces in Solutions

33.7K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
33.7K
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

63.1K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
63.1K
Common Ion Effect03:24

Common Ion Effect

41.7K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Châtelier’s principle. Consider the dissolution of silver iodide:
41.7K
Intermolecular Forces03:13

Intermolecular Forces

58.4K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
58.4K

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相关实验视频

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Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System
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在电解质溶液中的离子特异性泡凝聚力学.

Afsal Chakkam Palliyalil1, Ananthan Mohan1, Susmita Dash1

  • 1Department of Mechanical Engineering, Indian Institute of Science, Bangalore 560012, India.

Langmuir : the ACS journal of surfaces and colloids
|December 22, 2023
PubMed
概括

溶解的离子显著影响泡凝聚时间,影响工业过程. 这项研究揭示了NaCl和Na2SO4等电解质如何通过影响薄膜排水动力学来减缓凝聚.

科学领域:

  • 流体动力学 流体动力学
  • 合体和表面科学科学
  • 电化学 电化学 电化学

背景情况:

  • 泡凝聚在工业应用中至关重要,例如泡漂浮和热管理.
  • 液相中溶解离子的存在影响了气泡凝聚力学.
  • 了解泡和基板之间的薄电解质膜行为是控制凝聚的关键.

研究的目的:

  • 研究电解质度和离子类型对薄膜排水和泡凝聚的影响.
  • 开发一个包含表面张力梯度和电双层 (EDL) 效应的数值模型.
  • 阐明马兰戈尼应力和EDL在确定泡凝聚时间尺度中的作用.

主要方法:

  • 基于薄膜方程的数值模型的开发.
  • 包括依赖离子度的表面张力梯度和EDL.
  • 分析马兰戈尼应力和EDL对流体排水动态的影响.

主要成果:

  • 某些电解质 (NaCl,Na2SO4,NaI) 减缓了泡凝聚,而其他电解质 (HCl,HNO3) 的作用很小.
  • 电解质度增加增加了马兰戈尼的应力,减缓了排水,促进了坑的形成.
  • EDL和范德瓦尔斯力决定了水友基板上的最终薄膜动力学,导致稳定的电解质层.

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  • 较高的NaCl度降低了稳定膜厚度;Na2SO4在较小的厚度下稳定,这是由于离子价值.
  • 结论:

    • 电解质的组成和度是控制泡凝聚时间的关键因素.
    • 马兰戈尼应力和EDL相互作用在薄电解质薄膜的水力动力学中起着重要作用.
    • 这些发现为控制各种工业过程中的泡凝聚提供了洞察力.