用离子液体和它们的二元混合物从其与n-Hexadecane的混合物中提取Pyrrole
Sorfina Amran1, Muhammad Zulhaziman Mat Salleh1, Hanee F Hizaddin2
1Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, Bangi 43600, Malaysia.
Molecules (Basel, Switzerland)
|December 23, 2023
概括
离子液体 (ILs) 为燃料油脱提供了一种成本效益高的替代方案,而不是传统的脱. IL-IL混合物在从燃料中去除化合物的能力和选择性更强.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
- 绿色化学 绿色化学
背景情况:
- 传统的脱化是昂贵的,并且采用了恶劣的条件.
- 离子液体 (ILs) 正在成为燃料油提取性脱的高效溶剂.
研究的目的:
- 使用计算方法选潜在的离子液体 (ILs) 进行燃料油提取性脱.
- 通过实验验证所选IL及其混合物在去除化合物的性能.
主要方法:
- 真实溶剂导体样选模型 (COSMO-RS) 用于选173种IL.
- 使用选定的IL及其混合物从n-hexadecane提取pyrrole的实验液体液体提取.
- 应用了NRTL模型来关联实验的绑定线数据.
主要成果:
- 两个ILs,[EMIM][N(CN) ]和[EMIM][MeSO3],被选中进行实验研究.
- IL-IL混合物表现出高烯提取能力和选择性.
- 三级系统显示正倾斜,表明化合物对提取阶段的偏好亲和力.
结论:
- 离子液体-IL混合物对于提取性脱非常有效,提供更好的容量和选择性.
- 研究的IL系统显示出有希望的提取效率,可能减少溶剂需求.
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