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Updated: Jul 7, 2025

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

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关于在阿里亚化物和乙烯烯酸盐之间的 [3+2] 循环添加反应中中基中间体的问题

Ewa Dresler1, Przemysław Woliński2, Aneta Wróblewska3

  • 1Łukasiewicz Research Network-Institute of Heavy Organic Synthesis "Blachownia", Energetyków 9, 47-225 Kędzierzyn-Koźle, Poland.

Molecules (Basel, Switzerland)
|December 23, 2023
PubMed
概括

这项研究揭示了亚酸和乙烯烯酸盐之间的 [3+2] 循环添加反应遵循一个极性,单步机制. 之前提出的Zwitterionic中间体在主要反应途径中没有观察到.

关键词:
分子电子密度理论 分子电子密度理论[3+2]循环添加 [3+2]循环添加乙烯的使用方法亚化物是亚化物中的一种.这是一个机制机制.

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