马尔蒂托尔衍生的牺牲剂用于增强PCE和水泥糊之间的兼容性
Huan Wang1,2, Weixun Zhao2, Siqi Wang3
1Key Laboratory for Comprehensive Energy Saving of Cold Regions Architecture, Ministry of Education, Jilin Jianzhu University, Changchun 130118, China.
Materials (Basel, Switzerland)
|December 23, 2023
概括
一种新的牺牲剂 (SA),马尔蒂托-盐 (KN-lm),提高了混凝土的可加工性. 它提高了含粘土的水泥中的聚碳酸 (PCE) 兼容性,增加了19%的初始流动性.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 混凝土技术 混凝土技术
背景情况:
- 混凝土中的粘土干扰了聚碳酸 (PCE) 吸附到水泥颗粒上,降低了泥的可加工性.
- 这种相互作用限制了PCE超塑剂在富含粘土的水泥材料中的有效性.
研究的目的:
- 开发和评估一种新型牺牲剂 (SA),以改善含粘土的水泥泥中的PCE兼容性和性能.
- 研究SA通过粘土增强水泥糊的分散和流动性的机制.
主要方法:
- 合成一种马尔蒂托尔-盐阴 (KN-lm) 牺牲剂.
- 评估KN-lm对含粘土的水泥糊的流动性的影响.
- 使用总有机碳 (TOC),X射线衍射 (XRD) 和泽塔电位测量的分析.
主要成果:
- KN-lm显著增加了大约19%的含粘土的水泥泥的初始流动性.
- 通过静电相互作用,KN-lm优先吸附在粘土颗粒上,防止PCE吸附在粘土上.
- 在粘土中没有观察到晶体结构的变化,而水泥颗粒的分散性得到了改善.
结论:
- 马尔蒂托氨酸盐 (KN-lm) 作为一种有效的牺牲剂,用于含有粘土的水泥泥.
- KN-lm增强了PCE与含粘土的水泥的兼容性,改善了流动性和分散性.
- 优选的KN-lm吸附机制有效地阻碍了粘土水化扩张和PCE间隔.
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