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Updated: Jul 7, 2025

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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混合连接器二维共价有机框架,用于电化学不对称催化

Chen Yuan1,2, Shiguo Fu1, Xing Kang1

  • 1School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules and State Key Laboratory of Metal Matrix Composites, Shanghai 200240, P. R. China.

Journal of the American Chemical Society
|December 26, 2023
PubMed
概括

本研究介绍了用于电化学不对称催化物的合有机框架 (COF). 这些新型的COF可使有价值的化合物的高度选择性合成,促进可持续的化学生产.

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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