从石化废水中提升多组分溶解有机化学品的提升选择性阶段性吸附
Jinming Lei1, Ruifang Qi2, Sadam Hussain Tumrani3
1State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing, 100875, PR China; The Key Laboratory of Water and Sediment Sciences, Ministry of Education, School of Environment, Beijing Normal University, Beijing 100875, PR China.
The Science of the total environment
|December 27, 2023
概括
这项研究引入了采用活性炭和二氧化凝的两步吸附方法,有效地从石化废水中去除各种污染物,实现有机碳和生物毒性的高去除率.
科学领域:
- 环境科学 环境科学
- 水处理技术 水处理技术
- 吸附科学 吸附科学
背景情况:
- 石化废水含有复杂的溶解有机化学物质混合物,这给净化带来了重大挑战.
- 逐步选择性吸附是一种有前途的策略,用于加强处理这些复杂的废水.
研究的目的:
- 通过逐步吸附方法,加强从石化废水中去除多种溶解有机化学物质.
- 研究N,N-二甲基形式胺 (DMF),光溶解有机物 (FDOM) 和其他有机成分的选择性去除机制.
- 评估组合吸附剂的协同效应及其长期稳定性.
主要方法:
- 一个采用煤炭活性炭和二氧化凝的两步吸附过程.
- 选择性吸附机制的分析,包括疏水性,静电性和亲水性相互作用.
- 对溶解有机碳和生物毒性的去除效率的评估.
- 在多个吸附-脱附周期中评估吸附剂稳定性.
主要成果:
- 煤炭活性炭和二氧化凝的组合显示出协同效应,使得各种污染物可以被去除.
- 在石化废水中,溶解有机碳的去除率为80.5%,生物毒性为86.7%.
- 吸附剂性能在五个周期内保持稳定,表明可重复使用性良好.
- 化选择性吸附机制:用于疏水性有机物 (例如DMF) 的活性炭和用于水友性有机物的二氧化.
结论:
- 增强的两步吸附过程有效地从石化废水中去除多种污染物.
- 了解选择性吸附机制为优化废水处理策略提供了洞察力.
- 这种方法为复杂的工业废水深度处理提供了可行的解决方案.
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