消极双极层桥接的3D/2D矿异质连接,用于高效和稳定的p-i-n太阳能电池
Xiaoxiao Zang1, Shaobing Xiong1,2, Sheng Jiang1
1School of Physics and Electronic Science, East China Normal University, Shanghai, 200241, China.
Advanced materials (Deerfield Beach, Fla.)
|December 28, 2023
概括
一种新型的被动化双极层 (PDL) 增强了p-i-n矿太阳能电池 (PSC) 中的3D/2D矿异质连接. 这一战略克服了能源障碍,提高了这些关键太阳能设备的效率和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 固态物理 固态物理
背景情况:
- 矿太阳能电池 (PSC) 通过3D/2D异质连接提供高效率和稳定性.
- 然而,p-i-n架构面临着诸如能量水平不匹配和3D/2D接口上的重组等挑战.
研究的目的:
- 通过解决界面能量障碍和重组,为p-i-n PSCs开发一个高效的3D/2D异质连接.
- 为了提高p-i-n矿太阳能电池的性能和稳定性.
主要方法:
- 在3D矿层上加入一个薄的被动化双极层 (PDL).
- 在PDL修饰的3D矿上对2D矿进行连续沉积,形成3D/PDL/2D异质连接.
- 界面特性和设备性能的表征.
主要成果:
- 该PDL创建一个界面双极,调整能量水平和减少电子提取障碍.
- PDL的形成涉及与3D矿的共价结合,使表面缺陷被动化并抑制非辐射重组.
- 由此产生的3D/PDL/2D交叉 p-i-n PSC 实现了 24.85% 的功率转换效率,并具有强大的稳定性.
结论:
- 开发的3D/PDL/2D异质连接策略有效地解决了p-i-n PSC中的接口限制.
- 这种方法可以实现高性能和稳定的矿太阳能电池,与n-i-p设备相提并论.
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