通过表面增强的拉曼光谱仪在制食品中的酸盐的稳健和灵敏的确定
Yufei Wang1, Cui Zhang1, Ruiying Yu1
1Institute of Materia Medical, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan 250117, Shandong, China.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
|December 28, 2023
概括
一种新方法使用金银纳米粒子与表面增强拉曼光谱 (SERS) 快速准确地检测化食品中的化物. 这种方法通过可靠地测量有害酸盐含量来提高食品安全.
科学领域:
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
- 食品科学 食品科学 食品科学
背景情况:
- 食品中的亚酸盐是一个重要的健康问题.
- 准确和快速检测亚酸盐对于食品安全至关重要.
- 现有的方法可能缺乏实时监控的灵敏度或速度.
研究的目的:
- 开发一种强大,快速和灵敏的酸盐离子检测方法.
- 为了利用金银 (Au@Ag) 纳米粒子作为表面增强的拉曼光谱 (SERS) 基板.
- 为了验证该方法在制食品样本中的性能.
主要方法:
- 制造用于SERS应用的Au@Ag纳米粒子.
- 使用4-氨基基醇 (PATP) 将酸盐离子固定在SERS基底上.
- 使用SERS进行定量分析,并通过PATP进行内部校准.
主要成果:
- 在5.00-100.00μM范围内建立了酸盐检测 (R2 = 0.987) 的线性关系.
- 对于化物,达到0.17μM的低检测极限 (LOD).
- 在真实样本中表现出高选择性,良好的精度 (RSD < 7.00%) 和回收率 (101.42-107.35%).
结论:
- 拟议的SERS方法提供了一种可靠而敏感的方法来确定酸盐在制食品中的酸盐.
- 使用Au@Ag纳米颗粒可以提高检测能力.
- 这种方法在食品安全和监管监管方面具有重大潜力.
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