大气Cr的异质 (气体-固体) 化学:哈萨克斯坦阿斯塔纳的一个案例研究
Enoch Kwasi Adotey1, Mannix P Balanay2, Dhawal Shah1
1Department of Chemical and Materials Engineering, School of Engineering and Digital Sciences, Nazarbayev University, Astana, 010000, Kazakhstan.
Environmental pollution (Barking, Essex : 1987)
|December 28, 2023
概括
阿斯塔纳的六价 (Cr(VI)) 在阿斯塔纳
科学领域:
- 环境化学环境化学
- 大气科学 大气科学
- 毒理学 毒理学 毒理学
背景情况:
- 六价 (Cr(VI)) 是已知来自各种来源的人类致癌物.
- 了解颗粒物 (PM) 中的Cr6对公共健康至关重要.
- 大气中的物种化会影响其环境行为和风险.
研究的目的:
- 在阿斯塔纳的PM中量化大小分离的Cr (VI) 度.
- 为了研究大气中的Cr (VI) 气体-固体反应.
- 评估与空气中的Cr相关的潜在健康风险.
主要方法:
- 使用5级Sioutas级联冲击器进行颗粒大小分离.
- 使用微波辅助消化进行总Cr (VI) 分析.
- 测量Cr (VI) 度,以颗粒大小分数表示.
主要成果:
- 在最小尺寸分量 (<0.25微米) 中发现了最高的CrVI度,达到9.7 ng/m3.
- 总悬浮颗粒Cr(VI) 含量是参考度 (RfC) 的22倍.
- 夏季的Cr (VI) 含量明显高于秋季,这与气象和化学因素有关.
结论:
- 细颗粒Cr(VI) 由于深入肺部透,造成了显著的吸入风险.
- 在Cr (III) 和Cr (VI) 之间的气体固体反应可能控制大气中的物种化.
- 大气条件的季节性变化会影响Cr (VI) 度.
更多相关视频
07:24Combustion Chemistry of Fuels: Quantitative Speciation Data Obtained from an Atmospheric High-temperature Flow Reactor with Coupled Molecular-beam Mass Spectrometer
Published on: February 19, 2018
10.1K
08:37Measurement of H2S in Crude Oil and Crude Oil Headspace Using Multidimensional Gas Chromatography, Deans Switching and Sulfur-selective Detection
Published on: December 10, 2015
19.2K
相关概念视频
Catalysis
26.9K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
26.9K
Gas Chromatography: Introduction
2.0K
Gas chromatography (GC) is a technique for separating and analyzing volatile compounds in a sample. Its primary purpose is to identify and quantify components in complex mixtures, making it essential in fields such as environmental analysis, pharmaceuticals, and petrochemicals. GC is also called vapor-phase chromatography (VPC) or gas-liquid partition chromatography (GLPC).
In GC, a sample is vaporized and mixed with an inert carrier gas (the mobile phase), which transports it through a...
In GC, a sample is vaporized and mixed with an inert carrier gas (the mobile phase), which transports it through a...
2.0K
Atomic Absorption Spectroscopy: Atomization Methods
522
Atomic Absorption Spectroscopy (AAS) atomizes samples through flame atomization or electrothermal atomization. Flame atomization typically involves a nebulizer and spray chamber assembly to combine the sample with a fuel–oxidant mixture, creating a fine aerosol mist that enters a burner. Typically, the fuel and oxidant are combined in an approximately stoichiometric ratio. However, for atoms that are easily oxidized, a fuel-rich mixture may be more advantageous. Only about 5% of the...
522
