离子液体的粘度:理论和模型
Na Gao1, Ye Yang1, Zhiyuan Wang1
1State Key Laboratory of Heavy Oil Processing and High Pressure Fluid Phase Behavior & Property Research Laboratory, China University of Petroleum, Beijing 102249, P. R. China.
Chemical reviews
|December 29, 2023
概括
本综述总结了用于预测离子液体 (ILs) 压力-粘度-温度 (P-η-T) 行为的模型. 它推了强大的IL粘度模型,并强调了对这些多功能溶剂的未来研究需求.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 离子液体 (ILs) 具有独特的,可调节的特性,使其优于常规溶剂.
- 准确预测ILs的压力-粘度-温度 (P-η-T) 行为对于其更广泛的应用至关重要.
- 现有的IL粘度模型需要进行系统的评估和比较.
研究的目的:
- 审查和定量评估IL粘度的理论和经验模型.
- 引入用于粘度模型的热力学输入计算方法.
- 提出与IL相关的混合物粘度的预测方程.
主要方法:
- 为粘度模型引入热力学计算方法.
- 对IL粘度的理论,理论,半经验,经验和现象学模型的审查.
- 对纯 IL 和 IL 相关混合物的模型性能进行系统比较.
主要成果:
- 评估各种建模方法,包括那些与EoS或活动系数模型的合理论.
- 关于IL相关混合物的粘度的简单预测方程的建议.
- 不同粘度模型的预测能力的比较.
结论:
- 对大气压下IL粘度的可靠预测模型的建议.
- 确定P-η-T行为的一致理论和模型.
- 在IL粘度建模方面的剩余研究挑战概述.
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