在酸中形成的阳极氧化中染色玻璃效应
Sergey E Kushnir1, Nadezhda P Devyanina1, Ilya V Roslyakov1
1Lomonosov Moscow State University, Moscow 119991, Russia.
The journal of physical chemistry letters
|January 3, 2024
概括
合金 合金 是一种
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 电化学 电化学 电化学
背景情况:
- 阳极氧化 (AAO) 具有独特的特性,使其在先进的应用中具有价值.
- 酸电解质能够制造具有低孔隙性和高光学透明度的AAO,适合光子晶体.
研究的目的:
- 研究 (Al) 的结晶学方向如何影响AAO的特性.
- 了解对电化学氧化率,生长率,多孔性和折射率的影响.
主要方法:
- 使用1M H2SeO4电解质进行电化学氧化Al.
- 采用循环化机制制造AAO光子晶体 (PhCs).
- 通过光子带间隙的波长位置测量AAO增长率.
主要成果:
- 颗粒的晶体方向显著影响AAO的特性.
- 由于结晶学取向,在40-45V的化电压下,增长速度变化高达22.6%.
- 这种变化导致可见的"彩色玻璃效应".
结论:
- 晶体学定位是为光子晶体应用量身定制AAO属性的关键因素.
- 观察到的"彩色玻璃效应"提供了视觉指标的成长取决于方向.
- 基于酸的化为纳米技术提供了一条可控AAO制造的途径.
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