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由原始和补充方法确定的生物基多层材料的水蒸气传输特性
Manon Guivier1, Chloé Chevigny1, Sandra Domenek1
1Université Paris-Saclay, INRAE, AgroParisTech, UMR SayFood, 91120, 22 Place de l'Agronomie, Palaiseau, France.
Scientific reports
|January 3, 2024
概括
聚乳酸 (PLA) 薄膜上的超薄纳米纤维素和奇托桑涂层显著改变了水运输. 这些纳米层,即使在较低的重量百分比下,也会影响PLA的水蒸气吸收和扩散特性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术 纳米技术
背景情况:
- 聚乳酸 (PLA) 是一种可生物降解的聚合物,具有包装应用的潜力.
- 提高PLA的气体屏障特性,特别是水蒸气阻力,对于其更广泛的采用至关重要.
- 结合纳米纤维素等极性材料的多层薄膜显示出改善屏障性能的希望.
研究的目的:
- 为了研究和纳米纤维素的纳米层覆盖的聚乳酸 (PLA) 薄膜中的水运输现象.
- 了解这些超薄涂层对多层PLA膜整体水蒸气传输行为的影响.
- 评估不同类型的纳米纤维素及其与素的相互作用对屏障特性的影响.
主要方法:
- 动态蒸汽吸附 (DVS) 用于测量水蒸气吸收.
- 进行了长期的水蒸气吸附-扩散实验 (背面测量).
- 纳米纤维素涂层的特征及其与酸盐 (例如和离子键) 的相互作用.
主要成果:
- 纳米基托桑和纳米纤维素涂层,包括不到1重量%的薄膜,显著影响了PLA的水蒸气传输.
- 由于纳米涂层,多层膜的水蒸气吸收增加了14.6%.
- 纳米纤维素的类型 (CNF TEMPO,CNF,CNC) 和它与酸盐的相互作用影响了水吸附和扩散阻力.
- 负电荷的CNF TEMPO涂层形成了密集的网络,对水运输具有更高的抵抗力.
结论:
- 超薄纳米涂层可以显著改变PLA膜的水传输特性.
- 涂层和基板之间的协同效应对于准确的性能评估至关重要.
- 对于具有超薄屏障层的材料,传统的水蒸气透度测量可能不足.
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