粒子分散通过有异质吸引力的多孔介质
Wilfred Kwabena Darko1, Deepak Mangal2, Jacinta C Conrad1
1Department of Chemical and Biomolecular Engineering, University of Houston, Houston, Texas, 77204, USA. jcpalmer@uh.edu.
Soft matter
|January 3, 2024
概括
在多孔介质中的异质吸引力显著改变粒子运输. 增加的吸引异质性增加了低流量时的扭曲性和分散性,但在高流量时变得可以忽略不计.
科学领域:
- 物理 物理学 物理
- 化学 化学 化学
- 材料科学 材料科学 材料科学
背景情况:
- 多孔介质在组成和表面电荷方面表现出自然的变化.
- 这些变化在介质和运输的粒子之间产生异质的物理化学吸引力.
- 了解这些相互作用对于预测各种应用中的粒子运输至关重要.
研究的目的:
- 研究异质吸引力对纳米柱阵列中的粒子扩散和分散的影响.
- 阐明在不同的流量条件和吸引力异质性下控制粒子运输的机制.
主要方法:
- 使用了斯托克斯动力学 (SD) 模拟.
- 在几何上有序的纳米柱阵列中检查了粒子运输.
- 分析了不同吸引力异质性对扩散和水力动力分散的影响.
主要成果:
- 静静的运输涉及扩散和间歇性跳跃在有吸引力的井之间.
- 增加吸引力异质性导致扭曲性增加,非高斯位移分布,扩散性降低.
- 在较低的Péclet数 (Pe) 时,异质性增强了粒子分布的扩大和纵向分散.
- 在高Pe时,纵向分散对异质性变得不敏感,遵循泰勒-阿里斯行为.
结论:
- 不同质的吸引力显著影响有孔的介质中的粒子运输动态.
- 跳跃机制的主导地位随着吸引力异质性的增加而增加.
- 流量条件调节异质性对散射的影响,而向导主导的模式显示出较低的灵敏度.
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