活性炭/粘土/藻酸盐复合水凝膜的制备和染料吸附性质
Nasim Ullah1, Zarshad Ali1, Amir Sada Khan2
1Department of Chemistry, Hazara University Mansehra 21120 Khyber Pakhtunkhwa Pakistan zarshad11@yahoo.com.
RSC advances
|January 4, 2024
概括
一种新型的水凝膜,使用来自苏斯宾植物和改性粘土的活性碳,有效地从水中去除甲基红色染料. 这种吸附剂显示出高容量,并遵循伪二次动力学和弗洛伊德利希异热模型.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 聚合物科学 聚合物科学
背景情况:
- 由合成染料污染的废水造成环境风险.
- 开发高效且具有成本效益的吸附剂对于去除染料至关重要.
- 基于酸盐的水凝具有作为吸附材料的潜力.
研究的目的:
- 为了合成和描述一种用于甲基红色染料吸附的新型水凝膜.
- 为了研究水凝膜的吸附机制和性能.
- 评估吸附过程的热力学和动力学参数.
主要方法:
- 使用藻酸盐,活性炭 (来自susbine植物) 和改性蒙特莫里隆尼特粘土的水凝膜合成.
- 通过FTIR,SEM,EDX和TGA进行物理化学表征.
- 吸附实验用于确定pH值,吸附剂剂量,接触时间,温度和初始染料度的影响.
主要成果:
- 水凝膜对甲基红的最大吸附能力为248.13毫克g-1.
- 吸附动力学遵循伪二阶模型.
- 均衡数据与弗洛伊德利希等热量 (R2 = 0.994) 非常相符.
- 热力学分析表明了自发的,有利的和内热吸附.
结论:
- 制造的水凝膜是一种有前途的吸附剂,可以有效地从水溶液中去除甲基红色.
- 该研究提供了对吸附机制和染料去除的最佳条件的见解.
- 使用当地采购的材料 (subine植物) 提高了吸附剂的可持续性.
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