对耐温度和耐盐有机/无机复合共聚合物的合成和性能评估
Yunbao Zhang1, Jiamei Quan1, Chengzhou Wang1
1Key Laboratory of Enhanced Oil Recovery of Education Ministry, Northeast Petroleum University, Daqing, Heilongjiang Province, China.
Designed monomers and polymers
|January 5, 2024
概括
新的有机/无机复合四级共聚合物在高温,高盐油库环境中提供了更好的性能. 这些先进的聚合物与传统的三元共聚合物相比,具有更强的粘度保留和稳定性.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 石油工程是石油工程中的一个.
背景情况:
- 传统的聚合物在恶劣的油库条件 (高温,高盐度) 中表现出局限性.
- 有机/无机复合共聚物通过结合两种材料类型的优势提供了一个有希望的解决方案.
- 开发适应性高分子以提高石油回收能力对于具有挑战性的水库环境至关重要.
研究的目的:
- 合成和描述新的有机/无机复合四元共聚物.
- 为了评估这些新型共聚合物的温度和耐盐性.
- 为了将它们的性能与现有的三元共聚合物进行比较,用于油库应用.
主要方法:
- 通过沉聚合合成的AM/AMPS/Si-St三元共聚合物的合成.
- 纳入改造的纳米二氧化颗粒以创建AM/AMPS/Si-St/g-SiO2四级共聚合物.
- 使用FT-IR和SEM进行表征;在不同的条件下评估粘度和颗粒大小.
主要成果:
- 通过FT-IR和SEM证实了三元和四元共聚物的成功合成.
- 确定了优化的单体度和比率,以防止韦森伯格效应.
- 与三元共聚合物相比,四元共聚合物在高Na+和Mg2+环境中显示出约10%的粘度保留率.
- 四级共聚合物在150°C下保持结构完整而不降解,延长了它们的稳定运行时间.
结论:
- 开发的四级共聚合物在油库应用中表现出优越的热和盐耐受性.
- 这些先进材料在粘度保留和长期稳定性方面提供了显著的改进.
- 这项研究为制造高性能聚合物提供了一条可行的途径,以应对具有挑战性的下井条件.
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