在薄非平衡聚合物薄膜中的分子反弹应力放松中使用生成方法
Mithun Madhusudanan1, Mithun Chowdhury1,2
1Lab of Soft Interfaces, Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai 400076, India.
The Journal of chemical physics
|January 5, 2024
概括
薄膜中的聚合物链从不平衡状态放松,释放压力并增加. 这项研究使用露技术量化了这种放松过程,为聚合物链动态提供了洞察力.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
背景情况:
- 聚合物通过最大的结构状态达到平衡,从而增加系统.
- 螺旋涂层薄膜因拉伸而使聚合物链陷入低,不平衡状态.
- 压力放松和生成发生在聚合物薄膜随着时间的推移和通过化.
研究的目的:
- 为了确定聚三乙烯薄膜中的分子反弹应力放松时间.
- 根据生成,在聚合物薄膜中进行质量差异化转变稳定状态.
- 通过细分分子重新排列和过程来解释聚合物应力放松.
主要方法:
- 利用露水技术来测量压力放松时间.
- 在聚合物薄膜放松过程中分析了生成.
- 相关的放松时间与结构和分子重新排列.
主要成果:
- 量化了聚三乙烯薄膜中的分子反弹应力放松时间.
- 证明热生成与形态有关.
- 提供了压力放松的简化模型,涉及细分运动和超稳定状态.
结论:
- 露水技术有效地测量了聚合物薄膜中的应力松.
- 由热驱动的分子重新排列控制了向平衡的放松过程.
- 了解放松动态对于控制聚合物薄膜的性能和性能至关重要.
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