生物启发的微量基丰富电解质添加剂用于高速率和稳定的低温Zn离子电池
Fan Bu1,2, Yong Gao1, Wenbo Zhao1
1Frontiers Science Center for Flexible Electronics, Institute of Flexible Electronics, Northwestern Polytechnical University, Xi'an, 710072, China.
Angewandte Chemie (International ed. in English)
|January 5, 2024
概括
富含微量酸的电解质添加剂使得高性能,耐的离子电池. 这些添加剂增强离子动力学,防止腐蚀,使得在极低温度下稳定运行.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
背景情况:
- 离子电池的低温运行对于实际应用至关重要.
- 挑战包括缓慢的反应动力学和在降低温度下阳极腐蚀.
研究的目的:
- 使用新型电解质添加剂开发高性能,低温的离子电池.
- 研究添加剂对离子和阳极表面的双重重塑效应.
主要方法:
- 加入微量含基丰富的电解质添加剂,特别是α-D-葡萄糖 (αDG).
- 在零度以下的温度下对Zn//Zn电池和充满电池进行电化学测试.
- 对离子溶解和表面形态学的分析.
主要成果:
- 添加剂降低了电解质的结点到-55.3°C.
- 在-25°C下,Zn/Zn电池在2000小时内稳定循环,累积容量高 (5000 mAh cm−2).
- 一个充满电池的演示,在-50°C下稳定运行1万个周期.
结论:
- 富含基的添加剂有效地重塑离子溶解外和阳极表面.
- 这种双重改造增强了脱溶动动力学,抑制了腐蚀,使离子电池具有高速,稳定的低温性能.
相关概念视频
Batteries and Fuel Cells
27.4K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.4K
Ionic Bonds
118.5K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.5K
Ionic Strength: Effects on Chemical Equilibria
1.5K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
In this solution, the primary...
1.5K
Formation of Complex Ions
23.7K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.7K
Standard Electrode Potentials
43.9K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
43.9K
Ionic Bonding and Electron Transfer
41.6K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.6K


