使用基于纸张喷雾的质谱仪快速检测多和多基物质 (PFAS)
Md Tanim-Al Hassan1, Xingzhi Chen1, Praneeth Ivan Joel Fnu1
1Department of Chemistry and Environmental Science, New Jersey Institutes of Technology, University Heights, Newark, NJ 07102, USA.
Journal of hazardous materials
|January 7, 2024
概括
这项研究引入了一种快速的纸喷雾质谱法 (PS-MS) 方法,用于检测和多醇基物质 (PFAS). 这种技术简化了对水和食品包装的分析,为传统方法提供了快速的替代方案.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
背景情况:
- 采用质谱法 (MS) 进行传统的per-和多醇基物质 (PFAS) 分析通常是耗时的,因为需要大量的样品准备,包括提取和淡化.
- 需要更快,更有效的方法来检测各种环境和消费者矩阵中的PFAS.
研究的目的:
- 开发和验证用于直接检测PFAS的快速纸张喷雾质谱 (PS-MS) 技术.
- 评估PS-MS和修改后的淡化版本 (DPS-MS) 的适用性,用于分析饮用水,废水,食品包装和土壤等各种样本.
主要方法:
- 使用纸喷雾 (PS) 技术,采用三角过纸进行样本加载和电离,每样分析时间不到3分钟.
- 开发了脱盐纸喷雾质谱仪 (DPS-MS),通过快速淡化,电离和检测PFAS来克服盐矩阵的信号抑制.
- 研究了PFAS极性功能组与过纸的纤维素表面之间对于脱盐过程中分析物保留的水友性相互作用.
主要成果:
- 通过PS-MS,可以在饮用水,自来水和废水中直接和快速分析PFAS.
- 食品包装材料使用PS-MS直接分析PFAS污染.
- DPS-MS表现出高灵敏度 (检测极限:1.2-4.5 ppt) 和在分析土壤提取物和样本时的有效性,即使存在盐矩阵.
- 识别了关键的PFAS化合物,如每-甲酸 (PFOA) 和每-硫酸 (PFOS).
结论:
- 与传统方法相比,纸喷雾质谱 (PS-MS) 为PFAS分析提供了一种明显更快,更简单的方法.
- 开发的PS-MS和DPS-MS技术显示出对PFAS污染的日常,现实环境监测和分析有很大的潜力.
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