对不同应力下煤炭氧化热效应的研究
Jiangkun Chao1, Shuang Liu2, Rongkun Pan1
1School of Safety & Science Engineering, Henan Polytechnic University, Jiaozuo 454003, China; Collaborative Innovation Center of Coal Work Safety and Clean High Efficiency Utilization, Henan Polytechnic University, China.
The Science of the total environment
|January 7, 2024
概括
压力显著影响煤炭自燃 (CSC). 低压力促进CSC,而高压力通过改变氧化率和热性质来抑制CSC. 这项研究提供了对压力诱导的CSC机制的关键见解.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 采矿工程 采矿工程 采矿工程
背景情况:
- 狭窄的煤柱采矿将压力集中在柱子上,导致煤炭氧化变化.
- 了解压力对煤炭氧化和自燃的影响对于矿山安全至关重要.
研究的目的:
- 研究压力对煤炭氧化和自燃 (CSC) 的影响.
- 阐明压力在煤炭加热和氧化过程中影响热参数的机制.
主要方法:
- 在不同压力条件下,对煤样本进行了编程加热气体染色学合实验.
- 分析重点是气体衍生物,氧气消耗,CO/CO2度,释放热量和激活能量.
主要成果:
- 氧气消耗,CO/CO2释放和热强度在9 MPa应力时达到峰值,最初随应力而增加,然后随应力而减少.
- 激活能量呈现出V形趋势,在6MPa时最小化,表明低应力促进CSC,高应力抑制它.
- 煤的多孔性下降,热导率随着结构紧缩导致的压力增加而增加.
结论:
- 压力在煤炭自燃中起着双重作用,在低水平上促进燃烧,在高水平上抑制燃烧.
- 压力引起的结构变化,包括宏分子分解和紧度增加,影响热导率.
- 这项研究为减轻采矿过程中煤炭自燃的压力相关风险提供了理论基础.
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