一种基于铜 (I) 酸的光响应半导体二维协调聚合物
Tomoki Nishiyama1, Hirotaka Kitoh-Nishioka2, Senku Tanaka2,3
1Department of Chemistry, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.
Dalton transactions (Cambridge, England : 2003)
|January 10, 2024
概括
合成了一种含有铜(I) 硫酸盐和异类素的新型协调聚合物. 这种材料具有2D板结构,光发光和光导性.
科学领域:
- 材料科学 材料科学 材料科学
- 无机化学 无机化学
- 摄影化学的使用.
背景情况:
- 协调聚合物是具有可调节性质的先进材料.
- 铜 (I) 酸盐复合物由于其电子和光学特性而引起人们的兴趣.
研究的目的:
- 合成和表征一种新的配合聚合物,其中包括铜 (I) 硫酸盐和异诺林.
- 为了研究合成材料的光发光和光导特性.
主要方法:
- 合成协调聚合物[Cu(SCN) ((iqi) ],其中iqi是异类.
- 结构分析以确定二维 (2D) 板架构.
- 光物理测量用于评估光发光.
- 光导度测量以评估电荷传输特性.
主要成果:
- 成功合成了[Cu(SCN) ((iqi) ]协调聚合物.
- 确认一个2D板结构.
- 对三重金属对联体电荷转移 (3MLCT) 归因的光发光的观察.
- 展示光导行为. 光导行为.
结论:
- 合成的协调聚合物具有独特的二维结构.
- 该材料表现出有前途的光发光和光导性能,表明在光电子领域的潜在应用.
相关概念视频
Colors and Magnetism
11.7K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
11.7K
Coordination Number and Geometry
15.8K
For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to molecular geometry. The most common structures of the complexes in coordination compounds are octahedral, tetrahedral, and square planar.
15.8K
Photochemical Electrocyclic Reactions: Stereochemistry
1.8K
The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
Selection Rules: Photochemical Activation
1.8K

![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
