聚乙烯密封剂在热稳定前后的长期粘弹性行为
Urška Gradišar Centa1, Alen Oseli1, Mohor Mihelčič1
1Faculty of Mechanical Engineering, University of Ljubljana, Aškerčeva 6, 1000 Ljubljana, Slovenia.
Polymers
|January 11, 2024
概括
在绝缘玻璃中使用的聚乙烯密封剂在高温暴露后从线性结构变为分支结构. 这种结构变化增强了它们的类似固体的行为,改善了长期的性能和耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
背景情况:
- 聚乙烯 (PIB) 是多层绝缘玻璃的关键密封剂,对能源效率至关重要.
- 玻璃单元的高温 (>100°C) 会导致 PIB 的结构变化,从而缩短其寿命.
- 了解PIB的热行为对于耐用绝缘应用至关重要.
研究的目的:
- 研究商用聚乙烯 (PIB) 材料的依赖温度的粘弹性行为.
- 分析高温热处理对 PIB 结构和特性的影响.
- 提供用于模拟密封剂性能和预测寿命的数据.
主要方法:
- 利用时间-温度叠加 (tTS) 来研究长期粘弹性行为.
- 员工范集团-帕尔门图片分析热引起的结构变化.
- 从主曲线计算放松时间光谱,以确定分子重量分布.
主要成果:
- 热处理改变了PIB结构,从线性变为分支.
- 治疗后分子重量分布从单模向双模转移.
- 未经处理的PIB表现出粘性行为,而热稳定的PIB表现出增强的固体状行为.
结论:
- 热稳定显著改善了PIB密封剂的粘弹性特性.
- 该研究为预测玻璃单元中的PIB的功能和结构寿命提供了基础.
- 结果直接适用于有限元法 (FEM) 模拟密封剂性能.
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