观察老化对聚氨/聚氨酸urea涂层结构变化的影响
Paulina Mayer-Trzaskowska1, Mariola Robakowska2, Łukasz Gierz3
1Department of Light Elements Engineering, Faculty of Mechanical Engineering, Wroclaw University of Science and Technology, Foundry and Automation, Wybrzeże Wyspiańskiego 27, 50-370 Wroclaw, Poland.
Polymers
|January 11, 2024
概括
聚氨/聚氨基urea涂层暴露在自然,紫外线,化和热老化中显示出显著的变化. 化溶液的老化最严重影响了涂层粘附性和表面性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 表面工程是什么?表面工程是什么?
背景情况:
- 聚氨/聚氨基urea涂层对于表面保护至关重要.
- 了解衰老的影响对于物质的长寿至关重要.
- 环境因素显著影响涂层性能.
研究的目的:
- 调查各种老化条件对聚氨/聚氨酸urea涂层的影响.
- 描述因衰老引起的结构和物理化学变化.
- 评估老化对涂层粘附和表面性能的影响.
主要方法:
- 暴露于自然 (NC),紫外线 (UV),化 (NaCl) 和热 (TC) 的老化环境.
- 持续监测厚度,宏观和显微观测.
- 光谱 (FTIR),热 (TGA),水接触角度,表面自由能量和粘附测试.
主要成果:
- 老化显著改变了涂层的外观和拉开强度.
- 化溶液的老化证明了对粘附的最明显的影响.
- 物理化学性质,包括水接触角度和表面自由能量,都取决于老化条件.
结论:
- 老化条件极大地影响了聚氨/聚尿素涂层的完整性和性能.
- NaCl老化对涂层粘附构成最大的风险.
- 为了预测在各种环境压力下涂层的耐用性,全面的分析是必不可少的.
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