稀释对聚氨-水泥基复合表面涂料机械性能和微观结构的影响
Chao Xie1, Yufeng Shi1, Ping Wu2
1Civil Engineering Department, Lanzhou Jiaotong University, Lanzhou 730070, China.
Polymers
|January 11, 2024
概括
将稀释剂添加到聚氨涂层上会影响其机械性能和微观结构. 较高的稀释剂含量最初会提高强度,但随后会降低强度,而自由体积参数与这些机械变化相关.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 聚合物化学 聚合物化学
背景情况:
- 聚氨-水泥复合材料在土木工程中至关重要,通常用稀释剂进行修改以提高建筑适应性.
- 添加稀释剂会影响涂层性能,但其对机械性能和微观结构的影响仍未得到充分研究.
研究的目的:
- 研究不同稀释剂含量对聚氨涂层机械性能和微观结构的影响.
- 分析微观结构参数与宏观机械行为之间的相关性.
主要方法:
- 用控制的稀释剂度制备聚氨涂层.
- 微观结构分析使用正子灭终身光谱 (PALS).
- 通过通用材料测试进行机械性质测试 (抗拉强度,破裂延长).
- 使用扫描电子显微镜 (SEM) 观察断裂表面.
- 使用灰色关系理论进行相关性分析.
主要成果:
- 自由体积参数 (平均半径R,分数F) 呈现下降,随后随着稀释剂含量上升而增加.
- 拉力强度最初上升,然后下降,而破裂时的延长减少,然后随着稀释剂含量的变化而增加.
- 灰色关系分析表明R显著影响拉伸强度,F与破裂时的延伸有很强的相关性.
结论:
- 稀释剂含量极大地影响聚氨涂层的微观结构和机械性能.
- 自由体积特征与聚合物链流动性和宏观性质密切相关.
- 了解这些结构-性质关系是优化聚氨-水泥复合材料应用的关键.
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