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染料半导体的制备通过合聚合催化两种催化剂和应用到晶体管

Shiwei Ren^1,2, Wenqing Zhang³, Zhuoer Wang⁴

¹Zhuhai-Fudan Research Institute of Innovation, Hengqin 519000, China.

Molecules (Basel, Switzerland)

|January 11, 2024

概括

为有机晶体管合成了新型二基多罗罗 (DPP) 染料半导体. 一种DPP材料显示出增强的稳定性和更高的切换比率,突出显示了光电子的潜力.

科学领域:

材料科学材料科学材料科学
有机电子有机电子
聚合物化学聚合物化学

背景情况:

有机染料半导体正在成为下一代电子设备,特别是有机晶体管的关键材料.
基于Diketopyrrolopyrrole (DPP) 的染料由于其可调节的电子和光学特性,为光电子应用提供了有前途的性能.

研究的目的:

设计和合成两种基于染料核心的新二甲 (DPP) 染料材料.
研究不同催化剂条件对这些DPP材料的合成和性能的影响.
为了评估有机晶体管设备中合成材料的性能.

主要方法:

使用Stille合反应合成两种DPP染料核心材料.
分子重量和元素组成的表征.
评估热力学稳定性,光学性能和电化学能量水平.
有机晶体管设备的制造和测试.

主要成果:

两种催化剂都成功地准备了目标DPP结构,重量平均分子量和分散指数的变化.
与PDPP-2Py-2Tz II相比,PDPP-2Py-2Tz I具有较长的结合长度,并且表现出优越的热力学稳定性.
使用这些聚合物制造的晶体管设备显示出类似的中等电子流动性,但PDPP-2Py-2Tz I显示出更高的切换比率.

结论:

催化剂的选择影响了基于DPP的半导体的分子特性.
在DPP材料中,较长的结合长度与增强的热力学稳定性相关.
这些DPP染料材料显示了光电子应用的巨大潜力,特别是在有机晶体管中,PDPP-2Py-2Tz I是一个有前途的候选者.

关键词:

电子移动性的电子移动性能量带gapgap 能量带gap 光电子应用的应用.有机染料半导体有机染料半导体晶体管是一个晶体管.

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