关于通过与煤炭燃气化共同烧焦煤炭来提取贵金属元素的研究 粗渣
Jincheng Zhao1,2,3, Tao Yu1,2,3, Huan Zhang1
1Yan'an Key Laboratory of Low Carbon Synergistic Control Technology and Reservoir Protection for Oil and Gas Field Environmental Pollution, Shaanxi Fuquan Environmental Protection Technology Co., Ltd., Yan'an 727500, China.
Molecules (Basel, Switzerland)
|January 11, 2024
概括
这项研究从煤炭废物中提取有价值的和铁,使用联合烤和酸液. 优化条件实现了高金属回收,证明了废物回收利用的有希望的方法.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 煤渣 (CG) 和煤气化粗渣 (CGCS) 是具有危险性和资源潜力的工业副产品.
- 需要有效的方法来利用这些废物材料的高价值.
研究的目的:
- 研究共和硫酸出过程,从CG和CGCS中提取 (Al) 和铁 (Fe).
- 了解在共同烤过程中的激活行为和相变换机制.
主要方法:
- 同时烤CG和CGCS,然后进行H2SO4浸.
- 使用TG,XRD,FTIR和XPS进行表征.
- 吉布斯自由能量计算用于分析相位转换.
主要成果:
- 在优化条件下 (8:2 CG/CGCS比,600°C,1小时共同烤;30% H2SO4,90°C,5小时出) 产生了79.93%的总铁 (TFe) 和43.78%的Al3+出.
- 共同烤将高酸盐转化为甲高酸盐,形成西利曼酸盐和赫辛酸盐.
- 铁相通过血,磁,武,铁,赫辛和法雅连续转化.
结论:
- 在CG和CGCS中,共同烤显著激活了Al和Fe,用于酸洗.
- 该研究表明,煤炭废物材料的高价值利用是一个可行的途径.
- 酸和残留物都有进一步应用的潜力.
关键词:
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