用颗粒化技术对水泥复合材料中二氧化碳封存的性能评估
Jeong-Bae Lee1, Jun-Hyeong Kim2, Byeong-Gi Min1
1Department of Civil Engineering, Daejin University, 1007 Hoguk-ro, Pocheon-si 11159, Republic of Korea.
Materials (Basel, Switzerland)
|January 11, 2024
概括
提高水泥复合材料中二氧化碳 (CO2) 的吸收对于水泥行业至关重要. 这项研究发现,虽然涂层氧化颗粒 (CCHG) 是有前途的,但使用高炉渣 (BFS) 和飞灰 (FA) 由于它们的填充剂和波佐兰效应,会对二氧化碳封存产生负面影响.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 化学工程是化学工程的重要组成部分.
背景情况:
- 水泥行业是二氧化碳 (CO2) 排放的主要来源,需要有效的二氧化碳回收策略.
- 目前在水泥复合材料中的二氧化碳封存方法,如碳化,显示吸收能力有限.
- 提高水泥材料的二氧化碳吸收性能对于减轻工业环境影响至关重要.
研究的目的:
- 研究改善水泥复合材料中二氧化碳吸收的方法.
- 为了评估一种新的涂层氧化颗粒 (CCHG) 添加剂的有效性,用于二氧化碳封存.
- 了解补充性水泥材料,如高炉渣 (BFS) 和飞灰 (FA) 对二氧化碳封存的影响.
主要方法:
- 使用颗粒化技术制备氧化 (CH) 颗粒,然后涂层以防止过早反应.
- 涂层CH颗粒 (CCHG) 作为水泥重量5%的添加剂被纳入水泥样本中.
- 标本被治愈了91天,随后进行了二氧化碳吸收实验,以评估封存效率.
主要成果:
- 加入CCHG的目的是提高二氧化碳的吸收,但该研究发现BFS和FA添加剂有意想不到的负面影响.
- BFS和FA表现出充填效应,阻碍了水泥基质内的CO2通路.
- 与普通水泥糊相比,BFS和FA的pozzolanic性质消耗了氧化 (CH),进一步降低了二氧化碳封存潜力,导致BFS下降45.45%,FA下降63.64%.
结论:
- 在水泥复合材料中,二氧化碳封存性能受到材料多孔性和氧化 (CH) 的可用性显著的影响.
- 使用BFS和FA作为补充的水泥材料可能会对二氧化碳的封存产生不利影响,因为它们具有填充性和pozzolanic特性.
- 需要进一步的研究来优化在水泥材料中的二氧化碳封存策略,可能是通过改进添加物特性和了解水泥矩阵内的相互作用.
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