聚氨甘酸盐作为天然混合物和化物特性修饰剂
Marcin Włoch1, Maksymilian Toruńczak1, Janusz Datta1
1Department of Polymers Technology, Faculty of Chemistry, Gdańsk University of Technology, G. Narutowicza Str. 11/12, 80-233 Gdańsk, Poland.
Materials (Basel, Switzerland)
|January 11, 2024
概括
聚氨的化学回收产生糖酸盐,这是天然的有价值的修饰剂. 这种回收材料提高了的性能,并起到抗腐蚀作用,改善了材料的稳定性.
科学领域:
- 聚合物科学 聚合物科学
- 材料化学 材料化学
- 可持续材料 可持续材料
背景情况:
- 聚氨 (PU) 的化学回收提供了可持续的途径,以获得有价值的化学中间体.
- 糖解和糖解是关键的PU脱聚合方法,产生多或含尿的替代物.
- 这些回收产品可以作为聚合物复合材料的修饰剂.
研究的目的:
- 调查聚氨糖解盐对天然 (NR) 混合物和化物的特性的影响.
- 评估甘酸盐作为NR配方中的性能增强剂和抗降解剂的作用.
- 探索化学回收的PU作为NR应用中的修饰剂的潜力.
主要方法:
- 制备含有聚氨糖解的天然混合物.
- 对改性混合物的火山化动力学和膨胀行为的分析.
- 评估由此产生的火成的热力学和机械性能.
- 通过加快热老化试验评估材料稳定性.
主要成果:
- 发现聚氨糖解酸盐会影响火山化动力学,特别是促进活化.
- 甘油酸显示出抗降解性质,在热氧化衰老过程中增强稳定性.
- 与未经修改的样本相比,用甘油酸盐修改的火化物在机械性质上表现出更好的稳定性.
- 该研究证实了修饰剂对胀行为和热力学特征的积极影响.
结论:
- 化学回收的聚氨糖解盐可以有效地作为天然的修饰剂.
- 加入甘酸盐可以增强火山化过程,并提高天然火山化的耐老化性能.
- 这些发现强调了聚氨化学回收产品在技术中扩大应用的潜力.
相关概念视频
Plasticizers
75
Water-reducers, or plasticizers, are chemical admixtures used in concrete to improve strength and workability. These additives reduce the water-cement ratio without compromising workability, lower the cement content while maintaining the same workability, or increase workability to assist concrete placement in inaccessible areas.
Plasticizers function by using surface-active agents to create repulsive electrostatic forces between cement particles. This dispersion enhances the concrete's...
Plasticizers function by using surface-active agents to create repulsive electrostatic forces between cement particles. This dispersion enhances the concrete's...
75
Superplasticizers
85
Superplasticizers are advanced admixtures that enhance the workability of concrete by lowering the water content without compromising the strength of the material. These substances are highly effective water reducers, improving concrete flow, making it easier to work with, and enabling concrete to reach inaccessible areas or densely reinforced sections without mechanical vibration. The key components in superplasticizers are either sulfonated melamine or naphthalene formaldehyde condensates,...
85
Olefin Metathesis Polymerization: Overview
2.1K
Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
2.1K
Polymer Classification: Architecture
2.7K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
2.7K
Ziegler–Natta Chain-Growth Polymerization: Overview
3.3K
Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta...
3.3K
Additives and Fillers in Concrete
96
Additives and fillers are integral to enhancing the properties of concrete. Pozzolans and blast-furnace slag are additives or admixtures due to their reactions with calcium hydroxide released during cement hydration. Fillers, which are finely ground and similar in fineness to Portland cement, improve concrete attributes such as workability density, and reduce capillary bleeding or cracking. Some fillers possess hydraulic properties or participate in benign reactions within the cement paste.
The...
The...
96


